Application of a New Macrocyclic -PVC Electrode to Potentiometric Studies of Fe(III) Ion

Authors

  • H. Khanmohammadi -
  • H. Shafie -
  • M. Darvishpour -
  • M. H. Fekri -
  • R. Aminameli -
Abstract:

A PVC membrane Fe(III) ion selective electrode has been constructed using a new macrocyclic asmembrane carrier.The electrode exhibits a good potentiometric response for Fe(III) over a wideconcentration range 1.0×10-4 to 1.0×10-1M with a slope 19.4±0.5 mV/decade a and a working pHrange of 6.5-9.0. It has a fast response time ≤30s.The best performance was observed with themembrance having the 30.5% PVC,3.0% ligand, 61.0% acetophenone and 5.5% oleic acidcomposition.

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Journal title

volume 9  issue 3

pages  209- 2013

publication date 2012-07-01

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